A Fenton-like system of biochar loading Fe-Al layered double hydroxides (FeAl-LDH@BC) / H2O2 for phenol removal

被引:41
|
作者
Fan, Xiaoliang [1 ]
Cao, Qingqing [1 ]
Meng, Fanyue [1 ]
Song, Bing [1 ]
Bai, Zhongqiang [1 ]
Zhao, Yan [1 ]
Chen, Dandan [1 ,2 ]
Zhou, Yan [3 ]
Song, Min [1 ]
机构
[1] Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China
[2] Nanjing Normal Univ, Sch Energy & Mech Engn, Jiangsu Prov Key Lab Mat Cycling & Pollut Control, Nanjing 210042, Peoples R China
[3] Minist Ecol & Environm, Nanjing Inst Environm Sci, Nanjing 210042, Peoples R China
基金
中国国家自然科学基金;
关键词
Phenol; FeAl-LDH@BC; Catalyst; H2O2; ACID RED 1; RICE HUSK; DEGRADATION; CATALYST; ADSORPTION; WATER; OXIDATION; SOIL; PEROXYMONOSULFATE; NITROBENZENE;
D O I
10.1016/j.chemosphere.2020.128992
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
FeAl-layered double hydroxide (FeAl-LDH) supported by char was synthesized using the hydrothermal method in order to activate hydrogen peroxide (H2O2) to degrade phenol. The effects of char type, char synthesis amount, and several important parameters on the degradation were investigated. In addition, the physicochemical properties of FeAl-LDH@BC were revealed by instruments including the transmission electron microscope (TEM), X-ray diffraction (XRD), and Fourier-transform infrared (FT-IR). The results showed that the degradation efficiency of phenol (80 mg/L) by FeAl-LDH@BC0.25 was 85.28% at a pH of 3 and H2O2 concentration of 400 mg/L, and exhibited good reusability with a small amount of iron leaching. Electron paramagnetic resonance (EPR) and radical quenching results indicated that center dot OH radicals were the main participant during the degradation process, and XRD and FTIR spectra showed that FeAl-LDH was dissolved and rebuilt during the degradation process, and a small amount of iron was leached out resulting in the homogeneous catalysis. Hence, both homogeneous and heterogeneous processes occurred in the phenol oxidation process. Further soil remediation experiments showed that FeAl-LDH@BC0.25 could also effectively degrade phenol in soil, although the efficiency was lower than that in solution. (C) 2020 Published by Elsevier Ltd.
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页数:9
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