Porous Molecular Solids and Liquids

被引：204

作者：

Cooper, Andrew I. ^{[1
]}

机构：

[1] Univ Liverpool, Leverhulme Ctr Funct Mat Design, Dept Chem & Mat Innovat Factory, 51 Oxford St, Liverpool L7 3NY, Merseyside, England

来源：

ACS CENTRAL SCIENCE | 2017年 / 3卷 / 06期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

BONDED ORGANIC FRAMEWORK; INTRINSIC MICROPOROSITY PIMS; CRYSTAL ENERGY LANDSCAPES; CO2; ADSORPTION; CAGE COMPOUNDS; GAS; HYDROGEN; SEPARATION; STABILITY; DESIGN;

D O I：

10.1021/acscentsci.7b00146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Until recently, porous molecular solids were isolated curiosities with properties that were eclipsed by porous frameworks, such as metal organic frameworks. Now molecules have emerged as a functional materials platform that can have high levels of porosity, good chemical stability, and, uniquely, solution processability. The lack of intermolecular bonding in these materials has also led to new, counterintuitive states of matter, such as porous liquids. Our ability to design these materials has improved significantly due to advances in computational prediction methods.

引用

页码：544 / 553

页数：10

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