Preparation of mannitol-based ketal-linked porous organic polymers and their application for selective capture of carbon dioxide

被引：21
作者：
Li, Hui [1 ,2 ]
Ding, Xuesong [1 ]
Zhao, Yan-Chao [1 ]
Han, Bao-Hang [1 ]
机构：
[1] Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
POLYMER | 2016年 / 89卷
基金：
美国国家科学基金会;
关键词：
Porous organic polymers; Mannitol; Ketal-linkage; Carbon dioxide capture; Selective adsorption; SURFACE-AREA; GAS SORPTION; CO2; CAPTURE; LINKAGES SYNTHESIS; FRAMEWORKS; STORAGE; ADSORPTION; NETWORKS; HYDROGEN; CATALYSIS;
D O I：
10.1016/j.polymer.2016.02.024
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Four kinds of mannitol-based ketal-linked porous organic polymers (MKPOPs) were successfully synthesized through condensation reaction between aromatic acetyl monomers and mannitol, catalyzed by p-toluenesulfonic acid. The structure of resulting polymers was confirmed by Fourier transform infrared and solid-state C-13 nuclear magnetic resonance spectrum measurements. The porosities of MKPOPs were investigated by gas adsorption experiments and the results indicate high carbon dioxide uptake (up to 11.5 wt% at 273 K and 1.0 bar) for MKPOPs due to the predominant microporous and hydroxyl-rich structures. Remarkably, MKPOPs exhibit excellent selective adsorption performances for carbon dioxide over methane (9.9-14.2, IAST at 273 K and 1.0 bar). These studies are of significant importance for MKPOPs and their potential application in selective gas adsorption. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：112 / 118
页数：7
相关论文
共 52 条
  • [1] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture
    Banerjee, Rahul
    Phan, Anh
    Wang, Bo
    Knobler, Carolyn
    Furukawa, Hiroyasu
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. SCIENCE, 2008, 319 (5865) : 939 - 943
  • [2] CMPs as Scaffolds for Constructing Porous Catalytic Frameworks: A Built-in Heterogeneous Catalyst with High Activity and Selectivity Based on Nanoporous Metalloporphyrin Polymers
    Chen, Long
    Yang, Yong
    Jiang, Donglin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) : 9138 - 9143
  • [3] Mesoporous Conjugated Polycarbazole with High Porosity via Structure Tuning
    Chen, Qi
    Liu, De-Peng
    Zhu, Jian-Hua
    Han, Bao-Hang
    [J]. MACROMOLECULES, 2014, 47 (17) : 5926 - 5931
  • [4] Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation
    Chen, Qi
    Luo, Min
    Hammershoj, Peter
    Zhou, Ding
    Han, Ying
    Laursen, Bo Wegge
    Yan, Chao-Guo
    Han, Bao-Hang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (14) : 6084 - 6087
  • [5] Enantioselective addition of diethylzinc to aldehydes catalyzed by a new chiral β-amino alcohol derived from D-mannitol
    Cho, BT
    Chun, YS
    [J]. TETRAHEDRON-ASYMMETRY, 1998, 9 (09) : 1489 - 1492
  • [6] Carbon Dioxide Capture: Prospects for New Materials
    D'Alessandro, Deanna M.
    Smit, Berend
    Long, Jeffrey R.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) : 6058 - 6082
  • [7] Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction
    Ding, San-Yuan
    Gao, Jia
    Wang, Qiong
    Zhang, Yuan
    Song, Wei-Guo
    Su, Cheng-Yong
    Wang, Wei
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) : 19816 - 19822
  • [8] Mannitol-based acetal-linked porous organic polymers for selective capture of carbon dioxide over methane
    Ding, Xuesong
    Li, Hui
    Zhao, Yan-Chao
    Han, Bao-Hang
    [J]. POLYMER CHEMISTRY, 2015, 6 (29) : 5305 - 5312
  • [9] Calorimetric heats of adsorption and adsorption isotherms .2. O-2, N-2, Ar, CO2, CH4, C2H6, and SF6 on NaX, H-ZSM-5, and Na-ZSM-5 zeolites
    Dunne, JA
    Rao, M
    Sircar, S
    Gorte, RJ
    Myers, AL
    [J]. LANGMUIR, 1996, 12 (24) : 5896 - 5904
  • [10] THE DIRECT PRODUCTION OF TRI-SUBSTITUTED AND HEXA-SUBSTITUTED BENZENES FROM KETONES UNDER MILD CONDITIONS
    ELMORSY, SS
    PELTER, A
    SMITH, K
    [J]. TETRAHEDRON LETTERS, 1991, 32 (33) : 4175 - 4176
123456