Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid

被引：11
作者：
Timofeeva, Maria N. [1 ,2 ]
Panchenko, Valentina N. [1 ,2 ]
Lukoyanov, Ivan A. [1 ,2 ]
Jhung, Sung Hwa [3 ,4 ]
机构：
[1] RAS, Boreskov Inst Catalysis SB, Prospekt Akad Lavrentieva 5, Novosibirsk 630090, Russia
[2] Novosibirsk State Tech Univ, Prospekt K Marksa 20, Novosibirsk 630092, Russia
[3] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea
[4] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Daegu 41566, South Korea
来源：
REACTION KINETICS MECHANISMS AND CATALYSIS | 2021年 / 133卷 / 01期
关键词：
N-formylation; Aniline; Formic acid; Metal– organic framework; Brø nsted acidity; CONVENIENT PROCEDURE; SULFATED ZIRCONIA; BRONSTED ACIDITY; ROOM-TEMPERATURE; SECONDARY-AMINES; EFFICIENT; SPECTROSCOPY; SPECTRA;
D O I：
10.1007/s11144-021-01982-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Porous Zr-based metal-organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 degrees C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.
引用
收藏
页码：355 / 369
页数：15
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