High-pressure adsorption equilibria of methane and carbon dioxide on several activated carbons

被引：539

作者：

Himeno, S ^{[1
]}

Komatsu, T ^{[1
]}

Fujita, S ^{[1
]}

机构：

[1] Nagaoka Univ Technol, Dept Civil & Environm Engn, Niigata 9402188, Japan

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2005年 / 50卷 / 02期

关键词：

D O I：

10.1021/je049786x

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

High-pressure excess adsorption equilibria of methane and carbon dioxide on five microporous activated carbons were measured. Adsorption isotherms were obtained at temperatures ranging from (273 to 333) K and at pressures ranging from (0.5 to 6000) kPa using a static volumetric apparatus. The experimental data were analyzed using the Toth model and the Dubinin-Astakhov model. The isosteric enthalpies of adsorption and the limiting heat of adsorption for both adsorbates on all activated carbons were calculated using the Clausius-Clapeyron equations and the van't Hoff equations, respectively.

引用

页码：369 / 376

页数：8

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