Preparation and structural characterization of trimethylsilyl-substituted germylzinc halides, (Me3Si)3GeZnX (X = Cl, Br, and I) and silylzinc chloride, R(Me3Si)2SiZnCl (R = SiMe3 and Ph)

被引：37

作者：

Nanjo, M ^{[1
]}

Oda, T ^{[1
]}

Mochida, K ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 672卷 / 1-2期

关键词：

germylzinc halides; silylzinc chlorides; structure; X-ray diffraction; reactivity;

D O I：

10.1016/S0022-328X(03)00148-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trimethylsilyl-substituted germylzine halides, (Me3Si)(3)GeZnX (X = Cl, Br, and 1), and silylzinc chlorides, R(Me3Si)(2)SiZnCl (R = SiMe3, Ph), have been prepared and their molecular structures have been full determined by spectroscopic and single-crystal Xray diffraction methods. The germylzinc halides and silylzinc chlorides have dimeric structures consisting of two mu-halogen atoms. The reactivity of germylzinc chloride with substrates is also examined. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：100 / 108

页数：9

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