Catalytic hydrolysis of PNPP by cobalt (II) and manganese (III) complexes with (15-crown-5) salicylidenephenylimine

被引：0

作者：

Li, JZ ^{[1
]}

Li, SX ^{[1
]}

Xie, JQ ^{[1
]}

Zeng, W ^{[1
]}

Zhou, B ^{[1
]}

Qin, SY ^{[1
]}

机构：

[1] Sichuan Univ, Dept Chem, Chengdu 610064, Sichuan, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2004年 / 10期

关键词：

crowned salicylaldimine mono-Schiff base; manganese (III) and cobalt (II) complexes; mimic hydrolase; catalytic kinetics;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cobalt (II) and manganese (III) complexes with crowned salicylaldimine mono-Schiff base ligand have been employed as models to mimic hydrolase in catalytic hydrolysis of p-nitrophenyl picolinate(PNPP). The kinetics and the mechanism of PNPP hydrolysis have been investigated. The kinetic mathematical model of PNPP cleavage catalysed by these complexes has been proposed.

引用

页码：654 / 657

页数：4

共 17 条

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