Oxidative coupling of methane in the redox cyclic mode over the catalysts on the basis of CeO2 and La2O3

被引:22
作者
Greish, Alexander A. [1 ]
Glukhov, Lev M. [1 ]
Finashina, Elena D. [1 ]
Kustov, Leonid N. [1 ]
Sung, Jae-Suk [2 ]
Choo, Ko-Yeon [2 ]
Kim, Tae-Hwan [2 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Korea Inst Energy Res, Taejon 305343, South Korea
关键词
RARE-EARTH-OXIDES; SYNTHESIS GAS; LATTICE OXYGEN; ETHANE; DEHYDROGENATION; ETHYLENE; SODIUM;
D O I
10.1016/j.mencom.2010.01.011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 1% CeO2, 9% La2O3/SiO2 and 2% CeO2, 8% La2O3/SiO2 catalysts show reliable efficiency in the OCM reaction, as well as stable work in the redox cyclic mode. Selectivity to C-2 products remarkably increases if preliminary reduction of the catalyst by a small amount of hydrogen is used.
引用
收藏
页码:28 / 30
页数:3
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