Emerging Non-Aqueous Potassium-Ion Batteries: Challenges and Opportunities

被引:600
作者
Wu, Xianyong [1 ]
Leonard, Daniel P. [1 ]
Ji, Xiulei [1 ]
机构
[1] Oregon State Univ, Dept Chem, Gilbert Hall 153, Corvallis, OR 97331 USA
基金
美国国家科学基金会;
关键词
PRUSSIAN WHITE ANALOGS; K-ION; CATHODE MATERIAL; HIGH-CAPACITY; ANODE MATERIAL; ALKALI-METALS; IRON HEXACYANOFERRATE; STANDARD POTENTIALS; DOPED GRAPHENE; SUPERIOR ANODE;
D O I
10.1021/acs.chemmater.7b01764
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The ever-increasing demand for storing renewable energy sources calls for novel battery technologies that are of sustainably low levelized energy cost. Research into battery chemistry has evolved to a stage where a plethora of choices based on earth-abundant elements can be compared during their development. One of the emerging candidates is the nonaqueous potassium-ion battery. K-ion's unique properties as a charge carrier have aroused intense interest in exploring high-performing cathode and anode materials for this battery. Rapid progress has been made, where leading candidates of electrodes have been proposed, i.e., hard carbon as anode and Prussian white analogues as cathode. In this new battery technology's infancy, it is our opinion that the focus should be given to potentially scalable, inexpensive electrode materials and the understanding of their cycle-life-property correlations. It may be the ultralong cycle life that differentiates potassium-ion batteries from sodium-ion batteries in the future market.
引用
收藏
页码:5031 / 5042
页数:12
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