Superconductivity in a new iron pnictide oxide (Fe2As2)(Sr4(Mg, Ti)2O6)

被引:46
作者
Sato, Shinya [1 ,2 ]
Ogino, Hiraku [1 ,2 ]
Kawaguchi, Naoto [1 ,2 ]
Katsura, Yukari [3 ]
Kishio, Kohji [1 ,2 ]
Shimoyama, Jun-ichi [1 ,2 ]
Kotegawa, Hisashi [2 ,4 ]
Tou, Hideki [2 ,4 ]
机构
[1] Univ Tokyo, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] JST TRIP, Chiyoda Ku, Tokyo 1020075, Japan
[3] RIKEN, Magnet Mat Lab, Wako, Saitama 3510106, Japan
[4] Kobe Univ, Dept Phys, Kobe, Hyogo 6578501, Japan
关键词
D O I
10.1088/0953-2048/23/4/045001
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have discovered a new iron pnictide oxide superconductor (Fe2As2)(Sr-4(Mg, Ti)(2)O-6). This material is isostructural with (Fe2As2)(Sr4M2O6) (M = Sc, Cr, V), which were found in previous studies. The structure of this compound is tetragonal with a space group of P4/nmm and consists of the anti-fluorite type FeAs layer and perovskite-type block layer. The lattice constants are a = 3.935 angstrom and c = 15.952 angstrom for (Fe2As2)(Sr4MgTiO6). Bulk superconductivity with a T-c(onset) of similar to 26 K was observed for a partially Co-substituted sample. Moreover, Co-free and Ti-rich samples exhibited higher T(c(onset))s above 35 K, which were further enhanced by applying high pressures up to similar to 43 K.
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页数:5
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