Identification of the cobalt(II) chloride 'mixed' solvate Co4Cl8(H2O)4(MeCN)6:: the ionic structure trans-[Co(H2O)2(MeCN)4] trans-[Co(H2O)2(MeCN)2(CoCl4)2]

被引：4

作者：

Willey, GR ^{[1
]}

Aris, DR ^{[1
]}

Errington, W ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

TRANSITION METAL CHEMISTRY | 2000年 / 25卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1023/A:1007087505258

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the title compound features mononuclear octahedral Co-II cations, trans-[Co(H2O)(2)(MeCN)(4)](2+), and trinuclear anions, trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)](2-); the latter centrosymmetric units contain a central octahedral Co(H2O)(2)(MeCN)(2) moiety with two tetrahedral [CoCl4](2-) ligands. These two large ions are held in a network of intra- and inter-molecular hydrogen bonding.

引用

页码：534 / 536

页数：3

共 50 条

[21] Application of trans-[ZrO(curcumin)2(H2O)]•H2O in coloration of cotton fibers
Khorshidi, Alireza
Sadeghi, Nura
RESEARCH ON CHEMICAL INTERMEDIATES, 2017, 43 (02) : 1223 - 1233
[22] SynthesesandStructuresofTwoNewCobaltSupramolecularComplexes,[Co（4,4'-bipy）2（H2O）4]·[Co2（4,4'-bipy）3（H2O）8]·2TST·2（4,4'-bipy）·4H2Oand[Co（4,4'-bipy）2（H2O）4]DSNT·4,4'-bipy
余昀仿
韦永勤
吴克琛
结构化学, 2009, 28 (11) : 1519 - 1524
[23] Crystal structures of [Mn2(H2O)4(phen)2(C4H4O4)2] • 2 H2O and [Mn(phen)2(H2O)2][Mn(phen)2(C4H4O4)](C4H4O4) •7 H2O
Zheng, YQ
Lin, JL
Sun, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (05): : 1059 - 1065
[24] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
Zheng, YQ
Kong, ZP
JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
[25] Synthesis and crystal structure of [Zn(H2O)4(C4H2O4)] • H2O
XIe, HZ
Zheng, YQ
Shou, KQ
JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (15) : 1291 - 1297
[26] Syntheses and Structures of Two New Cobalt Supramolecular Complexes, [Co（4,4'-bipy）2（H2O）4]·[Co2（4,4'-bipy）3（H2O）8]·2TST·2（4,4'-bipy）·4H2O and [Co（4,4'-bipy）2（H2O）4]DSNT·4,4'-bipy
余昀仿
韦永勤
吴克琛
Chinese Journal of Structural Chemistry, 2009, (11) : 1519 - 1524
[27] Syntheses and Structures of Two New Cobalt Supramolecular Complexes, [Co(4,4′-bipy)2(H2O)4]•[Co2(4,4′-bipy)3(H2O)8]•2TST•2(4,4′-bipy)•4H2O and [Co(4,4′-bipy)2(H2O)4]DSNT•4,4′-bipy
Yu Yun-Fang
Wei Yong-Qin
Wu Ke-Chen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (11) : 1519 - 1524
[28] ISONICOTINAMIDE AS ENTERING LIGAND ON TRANS-[RU(NH3)4P(OME)3(H2O)]2+, TRANS-[RU(NH3)4P(OPR)3(H2O)]2+, TRANS-[RU(NH3)4P(OIPR)3(H2O)]2+, TRANS-[RU(NH3)4P (OBU)3(H2O)]2+
DONASCIMENTO, JC
FRANCO, DW
INORGANICA CHIMICA ACTA, 1986, 113 (01) : 55 - 60
[29] CRYSTAL AND MOLECULAR-STRUCTURE STUDIES OF [CO(H2O)6[2+[CO(H2O)HEDTA](2)-.2H2O AND [CO(H2O)HEDTA].2H2O
LOTT, S
ZUBKOWSKI, JD
VALENTE, EJ
PERRY, DL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 139 - INOR
[30] Synthesis and crystal structure of mer-[Co(C8H4O4)(C3H4N2)3(H2O)2]H2O
Benkanoun, A.
Fadela, Balegroune
Achoura, Guehria-Laidoudi
Slimane, Dahaoui
Claude, Lecomte
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C618 - C619

← 1 2 3 4 5 →