Merging N-Hydroxyphthalimide into Metal-Organic Frameworks for Highly Efficient and Environmentally Benign Aerobic Oxidation

被引：20

作者：

Wang, Man ^{[1
]}

Liang, Gan ^{[1
]}

Wang, Yunhao ^{[1
]}

Fan, Tao ^{[1
]}

Yuan, Baoling ^{[1
]}

Liu, Mingxian ^{[1
]}

Yin, Ying ^{[1
]}

Li, Liangchun ^{[1
]}

机构：

[1] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2021年 / 27卷 / 37期

基金：

中国国家自然科学基金;

关键词：

aerobic oxidation; heterogeneous catalysis; metalorganic frameworks; N-hydroxyphthalimide; nitroxyl radicals; MILD CONDITIONS; SELECTIVE OXIDATION; AROMATIC-ALDEHYDES; BENZYLIC ALCOHOLS; NITROXYL RADICALS; MOLECULAR-OXYGEN; SOLID CATALYSTS; BUTYL NITRITE; POLAR; PERFORMANCE;

D O I：

10.1002/chem.202100987

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two highly efficient metal-organic framework catalysts TJU-68-NHPI and TJU-68-NDHPI have been successfully synthesized through solvothermal reactions of which the frameworks are merged with N-hydroxyphthalimide (NHPI) units, resulting in the decoration of pore surfaces with highly active nitroxyl catalytic sites. When t-butyl nitrite (TBN) is used as co-catalyst, the as-synthesized MOFs are demonstrated to be highly efficient and recyclable catalysts for a novel three-phase heterogeneous oxidation of activated C-H bond of primary and secondary alcohols, and benzyl compounds under mild conditions. Based on the high efficiency and selectivity, an environmentally benign system with good sustainability, mild conditions, simple work-up procedure has been established for practical oxidation of a wide range of substrates.

引用

页码：9674 / 9685

页数：12

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