Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

被引：54

作者：

Hevia, E ^{[1
]}

Gallagher, DJ ^{[1
]}

Kennedy, AR ^{[1
]}

Mulvey, RE ^{[1
]}

O'Hara, CT ^{[1
]}

Talmard, C ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 21期

关键词：

D O I：

10.1039/b410293b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.

引用

页码：2422 / 2423

页数：2

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