A novel reagent-assisted mechanochemical method for nickel recovery from lateritic ore

被引:34
作者
Cetintas, Seda [1 ]
Yildiz, Ufuk [1 ]
Bingol, Deniz [1 ]
机构
[1] Kocaeli Univ, Fac Sci & Arts, Chem Dept, TR-41380 Kocaeli, Turkey
关键词
High energy milling; Lateritic ore; Mechanochemical conversion; Nickel recovery; RSM approach; RESPONSE-SURFACE METHODOLOGY; CENTRAL COMPOSITE DESIGN; SULFURIC-ACID; LIMONITIC LATERITE; ACTIVATION PRETREATMENT; MECHANICAL ACTIVATION; ATMOSPHERIC-PRESSURE; SAPROLITIC LATERITE; VALUABLE METALS; OPTIMIZATION;
D O I
10.1016/j.jclepro.2018.07.212
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A novel method for nickel recovery from lateritic ore was proposed. The method consisted of mechanochemical conversion in the presence of a reagent, ammonium carbonate or sodium hydroxide then followed by an acid leaching. The study presents the recovery of nickel from lateritic ore at low temperature and lower acid consumption to overcome the disadvantages of traditional metallurgical processes such as high temperature, high acid concentration, high cost and material requirements. Ore samples, both raw and mechanochemically treated, were characterized by different techniques such as Fourier transform infrared, X-ray diffraction, scanning electron microscope, thermogravimetry and differential scanning calorimetry. The leaching mechanism was defined as both chemically and diffusion controlled by shrinking core model. The optimization conditions for both mechanochemical conversion and atmospheric leaching processes were evaluated by response surface methodology to clearly demonstrate the advantages of the proposed method over conventional methods. The results of this study which included a combination of reactive-assisted mechanochemical process as a pretreatment and acid leaching reveal that high efficiency nickel recovery from the lateritic ore can be achieved with higher efficiency and lower iron content even at low temperatures and acid concentrations with shorter leaching time. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:616 / 632
页数:17
相关论文
共 64 条
[1]   Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton's peroxidation [J].
Ahmadi, M ;
Vahabzadeh, F ;
Bonakdarpour, B ;
Mofarrah, E ;
Mehranian, M .
JOURNAL OF HAZARDOUS MATERIALS, 2005, 123 (1-3) :187-195
[2]  
ALTA Metallurgical services, 2013, LAT STILL FRONT NICK
[3]  
[Anonymous], 2011, US Patent Application, Patent No. [2011/0116, 996, 20110116996]
[4]  
Ayanda O S., 2011, Journal of Minerals Materials Characterization Engineering, V10, P1457
[5]  
Aydoan S., 2005, J. Fac. Eng. Arch. Selcuk Univ, V20, P55
[6]   Plant-Mediated Synthesis of Silver Nanoparticles and Their Stabilization by Wet Stirred Media Milling [J].
Balaz, Matej ;
Balazova, L'udmila ;
Daneu, Nina ;
Dutkova, Erika ;
Balazova, Miriama ;
Bujnakova, Zdenka ;
Shpotyuk, Yaroslav .
NANOSCALE RESEARCH LETTERS, 2017, 12
[7]   Mechanical activation in hydrometallurgy [J].
Baláz, P .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2003, 72 (1-4) :341-354
[8]   The role of mechanical activation on atmospheric leaching of a lateritic nickel ore [J].
Basturkcu, Huseyin ;
Acarkan, Neset ;
Gock, Eberhard .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2017, 163 :1-8
[9]   Response surface methodology (RSM) as a tool for optimization in analytical chemistry [J].
Bezerra, Marcos Almeida ;
Santelli, Ricardo Erthal ;
Oliveira, Eliane Padua ;
Villar, Leonardo Silveira ;
Escaleira, Luciane Amlia .
TALANTA, 2008, 76 (05) :965-977
[10]   Production of SrCO3 and (NH4)2SO4 by the dry mechanochemical processing of celestite [J].
Bingol, Deniz ;
Aydogan, Salih ;
Bozbas, Seda Karayunlu .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (02) :834-838