Wittig reaction of 2,2-disubsitituted cyclopentane-1,3-dione

被引：0

作者：

Cao, YR ^{[1
]}

Ge, CS ^{[1
]}

Hu, Z ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 21卷 / 01期

关键词：

2,2-disubsitituted cyclopentane-1,3-dione; Wittig reaction; X-ray;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

During of studying the Wittig Reaction of 2,2-disubsitituted cyclopentane-1,3-dione, it was found that the product of the Wittig reaction was an alcohol rather than an olefin when sodium hydroxide was used as base, just like the product of Grignard Reaction. A pair of cis, trans isomers was separated and the crystal structure of the cis isomer was determined by X-ray diffraction analysis. The probable mechanism for the novel product was proposed.

引用

页码：60 / 63

页数：4

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