Spectroscopic characterization and crystal structure of trifluoromethyl iodine(III) chloride trifluoracetate (CF3I(Cl)OCOCF3)

被引：0

作者：

Minkwitz, R ^{[1
]}

Berkei, M ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 11期

关键词：

iodine(III); structure elucidation; vibrational spectroscopy;

D O I：

10.1002/1521-3749(200011)626:11<2325::AID-ZAAC2325>3.0.CO;2-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ternary iodine(III) compound CF3I(Cl)OCOCF3 is obtained by reaction between CF3I(Cl)F and OCOCF3 is obtained by reaction between CF3I(Cl)F and (CH3)(3)SiOCOCF3 at -50 degreesC. The molecule was characterized by vibrational spectra, NMR-spectra, and a crystal structure analysis. CF3I(Cl)OCOCF3 crystallizes monoclinic in the space group P2(1)/c with a = 1102.7(1) pm, b = 785.6(1) pm, c = 989.7(1) pm, and beta = 101.34(1)degrees.

引用

页码：2325 / 2329

页数：5

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