A novel anode material of antimony nitride for rechargeable lithium batteries

被引：36
作者：
Sun, Qian
Li, Wen-Jing
Fu, Zheng-Wen [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
SOLID STATE SCIENCES | 2010年 / 12卷 / 03期
关键词：
Sb3N; Anode; Electrochemical reaction; Rechargeable lithium batteries; THIN-FILM LITHIUM; ION BATTERIES; ELECTROCHEMICAL REACTION; SOLVOTHERMAL SYNTHESIS; SPECTRUM; SBN; POWDERS; COSB3;
D O I：
10.1016/j.solidstatesciences.2009.12.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Antimony nitride thin film has been successfully fabricated by magnetron sputtering method and its electrochemistry with lithium was investigated for the first time. The reversible discharge capacity of Sb3N/Li cells cycled between 0.3 V and 3.0 V was found above 600 mAh/g. By using transmission electron microscopy and selected area electron diffraction measurements, the conversion reaction of Sb3N into Li3Sb and Li3N was revealed during the lithium electrochemical reaction of Sb3N thin film electrode. The high reversible capacity and the good cycleability made Sb3N one of promising anode materials for future rechargeable lithium batteries. (C) 2009 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：397 / 403
页数：7
相关论文
共 31 条
[1]   Electrochemical reaction of lithium with the CoSb3 skutterudite [J].
Alcántara, R ;
Fernández-Madrigal, FJ ;
Lavela, P ;
Tirado, JL ;
Jumas, JC ;
Olivier-Fourcade, J .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (10) :2517-2521
[2]   Thin-film lithium and lithium-ion batteries [J].
Bates, JB ;
Dudney, NJ ;
Neudecker, B ;
Ueda, A ;
Evans, CD .
SOLID STATE IONICS, 2000, 135 (1-4) :33-45
[3]   Electrodeposited Sb and Sb/Sb2O3 nanoparticle coatings as anode materials for Li-ion batteries [J].
Bryngelsson, Hanna ;
Eskhult, Jonas ;
Nyholm, Leif ;
Herranen, Merja ;
Alm, Oscar ;
Edstrom, Kristina .
CHEMISTRY OF MATERIALS, 2007, 19 (05) :1170-1180
[4]   A simple route to high performance nanometric metallic materials for Li-ion batteries involving the use of cellulose:: The case of Sb [J].
Caballero, Alvaro ;
Morales, Julian ;
Sanchez, Luis .
JOURNAL OF POWER SOURCES, 2008, 175 (01) :553-557
[5]   Zn4Sb3(-C7) powders as a potential anode material for lithium-ion batteries [J].
Cao, GS ;
Zhao, XB ;
Li, T ;
Lu, CP .
JOURNAL OF POWER SOURCES, 2001, 94 (01) :102-107
[6]   ABSORPTION SPECTRUM OF SBN [J].
CIACH, S ;
THISTLETHWAITE, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (08) :3381-+
[7]   The pure rotational spectra and hyperfine constants of SbN and SbP [J].
Cooke, SA ;
Gerry, MCL .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (19) :4579-4585
[8]   Emission spectrum of antimony nitride [J].
Coy, N ;
Sponer, H .
PHYSICAL REVIEW, 1940, 58 (08) :709-713
[9]   Structural transformations in intermetallic electrodes for lithium batteries -: An in situ x-ray diffraction study of lithiated MnSb and Mn2Sb [J].
Fransson, LML ;
Vaughey, JT ;
Edström, K ;
Thackeray, MM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (01) :A86-A91
[10]   Electrochemical reactions of lithium with transition metal nitride electrodes [J].
Fu, ZW ;
Wang, Y ;
Yue, XL ;
Zhao, SL ;
Qin, QZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (07) :2236-2244
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