Boost sodium-ion batteries to commercialization: Strategies to enhance initial Coulombic efficiency of hard carbon anode

被引:261
作者
Zhang, Minghao [1 ]
Li, Yu [1 ]
Wu, Feng [1 ,2 ]
Bai, Ying [1 ]
Wu, Chuan [1 ,2 ]
机构
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Environm Sci & Engn, Beijing 100081, Peoples R China
[2] Collaborat Innovat Ctr Elect Vehicles Beijing, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
Hard carbon anodes; Sodium-ion batteries; Initial Coulombic efficiency; Commercialization; SOLID-ELECTROLYTE INTERPHASE; HIGH-PERFORMANCE ANODE; NITROGEN-DOPED CARBON; NA-ION; HIGH-CAPACITY; MECHANISTIC INSIGHTS; STORAGE PERFORMANCE; ENERGY-STORAGE; POROUS CARBON; ANATASE TIO2;
D O I
10.1016/j.nanoen.2020.105738
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sodium-ion batteries (SIBs) are regarded as one of the most promising candidates for large-scale energy storage system due to low cost and inexhaustible sodium reserves. The commercialize application of SIBs relies on the development of advanced cathode and anode materials. Among the various available anode materials, hard carbon material is considered to be the most potential anode material, which presents appropriate sodiation/ desodiation electric potential, high capacity, and simple synthesis method. However, the insufficient initial Coulombic efficiency (ICE) of hard carbon severely restricts the practical commercialization in SIBs. Hence, we review the influence elements that cause an inadequate ICE of hard carbon, such as the decomposition of electrolytes, high defects concentration, excessive surface functional groups, and irreversible sodium ions and so on. In order to obtain a moderate ICE, strategies including structure and morphology modification, defect and surface engineering, composition adjustment, electrolyte and binder optimization, material pre-treatment are confirmed to be effective. This review provides a further understanding of obtaining hard carbon electrodes with high ICE, which will contribute to the prosperity of SIBs in the near future.
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页数:19
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共 150 条
  • [111] Facile synthesis of high performance hard carbon anode materials for sodium ion batteries
    Sun, Ning
    Liu, Huan
    Xu, Bin
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (41) : 20560 - 20566
  • [112] A Flexible Sulfur-Enriched Nitrogen Doped Multichannel Hollow Carbon Nanofibers Film for High Performance Sodium Storage
    Sun, Xizhen
    Wang, Changlai
    Gong, Yue
    Gu, Lin
    Chen, Qianwang
    Yu, Yan
    [J]. SMALL, 2018, 14 (35)
  • [113] A Computational Chemical Insight into Microscopic Additive Effect on Solid Electrolyte Interphase Film Formation in Sodium-Ion Batteries: Suppression of Unstable Film Growth by Intact Fluoroethylene Carbonate
    Takenaka, Norio
    Sakai, Hirofumi
    Suzuki, Yuichi
    Uppula, Purushotham
    Nagaoka, Masataka
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (32) : 18046 - 18055
  • [114] Ultrasound-assisted synthesis of sodium powder as electrode additive to improve cycling performance of sodium-ion batteries
    Tang, Jialiang
    Kye, Daniel Kyungbin
    Pol, Vilas G.
    [J]. JOURNAL OF POWER SOURCES, 2018, 396 : 476 - 482
  • [115] Ab initio study of sodium intercalation into disordered carbon
    Tsai, Ping-chun
    Chung, Sai-Cheong
    Lin, Shih-kang
    Yamada, Atsuo
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (18) : 9763 - 9768
  • [116] Hierarchical Nanospheres Constructed by Ultrathin MoS2 Nanosheets Braced on Nitrogen-Doped Carbon Polyhedra for Efficient Lithium and Sodium Storage
    Tu, Fengzhang
    Han, Yu
    Du, Yichen
    Ge, Xufang
    Weng, Wangsuo
    Zhou, Xiaosi
    Bao, Jianchun
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (02) : 2112 - 2119
  • [117] Multiple Active Sites of Carbon for High-Rate Surface-Capacitive Sodium-Ion Storage
    Wang, Guang
    Shao, Meng
    Ding, Huarui
    Qi, Ying
    Lian, Jiabiao
    Li, Sheng
    Qiu, Jingxia
    Li, Huaming
    Huo, Fengwei
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (38) : 13584 - 13589
  • [118] Kelp-derived hard carbons as advanced anode materials for sodium-ion batteries
    Wang, Pengzi
    Zhu, Xiaoshu
    Wang, Qiaoqiao
    Xu, Xin
    Zhou, Xiaosi
    Bao, Jianchun
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (12) : 5761 - 5769
  • [119] Sulfur covalently bonded graphene with large capacity and high rate for high-performance sodium-ion batteries anodes
    Wang, Xiaolei
    Li, Ge
    Hassan, Fathy M.
    Li, Jingde
    Fan, Xingye
    Batmaz, Rasim
    Xiao, Xingcheng
    Chen, Zhongwei
    [J]. NANO ENERGY, 2015, 15 : 746 - 754
  • [120] Analysis of the Stable Interphase Responsible for the Excellent Electrochemical Performance of Graphite Electrodes in Sodium-Ion Batteries
    Wang, Zhaohua
    Yang, Haoyi
    Liu, Yiran
    Bai, Ying
    Chen, Guanghai
    Li, Ying
    Wang, Xinran
    Xu, Huajie
    Wu, Chuan
    Lu, Jun
    [J]. SMALL, 2020, 16 (51)