A palladium-catalyzed oxidative cross-coupling reaction between aryl pinacol boronates and H-phosphonates in ethanol

被引：14
作者：
Chen, Te-Hsuan [1 ]
Reddy, Daggula Mallikarjuna [1 ]
Lee, Chin-Fa [1 ]
机构：
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
来源：
RSC ADVANCES | 2017年 / 7卷 / 48期
关键词：
BOND-FORMING REACTIONS; SECONDARY PHOSPHINE OXIDES; ARYLBORONIC ACIDS; P-ARYLATION; C-N; REGIOSELECTIVE SYNTHESIS; DIPHENYLPHOSPHINE OXIDE; GENERAL PROCEDURE; VINYL HALIDES; BIPOLAR HOST;
D O I：
10.1039/c7ra04619g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first successful oxidative coupling reaction of aryl pinacol boronic esters with H-phosphonates to deliver aryl phosphorous compounds is reported herein. These reactions between aryl boronic reagents and H-phosphonates were carried out synergistically using a Pd catalyst, additive and oxidant. Without using bases and ligands, phosphorylation was accomplished in an environmentally-friendly manner under mild conditions in ethanol.
引用
收藏
页码：30214 / 30220
页数：7
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