Molecules under extreme conditions: Chemical reactions at high pressure

被引:102
作者
Schettino, V
Bini, R
机构
[1] European Lab Nonlinear Spectroscopy, LENS, I-50019 Florence, Italy
[2] INFM, I-50019 Florence, Italy
[3] Univ Florence, Dipartimento Chim, I-50019 Florence, Italy
关键词
D O I
10.1039/b301381b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The basic features of diamond anvil cells and of the available techniques to study chemical reactions at ultrahigh pressures are reviewed. A number of study cases including reactions of simple molecular systems (like nitrogen, carbon dioxide and monoxide, nitrous oxide), of unsaturated compounds (like acetylene, butadiene, propylene, cyano derivatives) and of aromatics are discussed to illustrate the perspectives of chemical reactivity at ultrahigh pressures.
引用
收藏
页码:1951 / 1965
页数:15
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