Thermodynamic and Differential Entropy under a Change of Variables

被引:34
作者
Hnizdo, Vladimir [1 ]
Gilson, Michael K. [2 ]
机构
[1] NIOSH, Hlth Effects Lab Div, Morgantown, WV 26505 USA
[2] Univ Maryland, Inst Biotechnol, Ctr Adv Res Biotechnol, Rockville, MD 20850 USA
来源
ENTROPY | 2010年 / 12卷 / 03期
关键词
thermodynamic entropy; Shannon entropy; spatial entropy; non-Cartesian coordinates; canonical transformation; Jacobian; CONFIGURATIONAL ENTROPY;
D O I
10.3390/e12030578
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. We show that a canonical change of variables can, indeed, alter the spatial component of the thermodynamic entropy just as it alters the differential Shannon entropy. However, there is also a momentum part of the entropy, which turns out to undergo an equal and opposite change when the coordinates are transformed, so that the total thermodynamic entropy remains invariant. We further more show how one may correctly write the change into talent ropy for an isothermal physical process in any set of spatial coordinates.
引用
收藏
页码:578 / 590
页数:13
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