Incoherent inelastic neutron scattering, Raman and IR absorption studies on 1,8-bis(dimethylamino)naphthalene and its protonated forms

被引：14

作者：

Pawlukojc, A

Natkaniec, I

Grech, E

Baran, J

Malarski, Z

Sobczyk, L ^{[1
]}

机构：

[1] Wroclaw B Beirut Univ, Fac Chem, PL-50383 Wroclaw, Poland

[2] Joint Inst Nucl Res, Dubna 141980, Russia

[3] Tech Univ Szczecin, Inst Fundamental Chem, PL-71065 Szczecin, Poland

[4] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1998年 / 54卷 / 03期

关键词：

vibrational spectra; proton sponge; hydrogen bonding;

D O I：

10.1016/S1386-1425(97)00237-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The incoherent inelastic neutron scattering (IINS), Raman and IR absorption spectra were measured and ab initio calculation studies were performed on 1,8-bis(dimethylamino)naphthalene (DMAN-proton sponge) and its protonated form. The IINS technique appeared to be very effective in studies of low frequency vibrations into which the methyl and dimethylamino groups are involved. Spectacular effects are observed on protonation of DMAN with respect to the N(CH3)(2) deformation and CH3 torsional modes in the range below 300 cm(-1). (C) 1998 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：439 / 448

页数：10

相关论文

共 21 条

[1] STRAIN EFFECTS ON AMINE BASICITIES [J].

ALDER, RW .

CHEMICAL REVIEWS, 1989, 89 (05) :1215-1223

[2] Crystal chemistry of tetraradial species .8. Mix and match: Cation geometry, ion packing, hydrogen bonding, and pi-pi interactions in cis-2,2'-bipyridinium(1+) and 1,10-phenanthrolinium(1+) tetraphenylborates - And what about proton sponges? [J].

Bakshi, PK ;

Cameron, TS ;

Knop, O .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1996, 74 (02) :201-220

[3] STRUCTURE OF THIOCYANATE SALT OF 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE (DMANH+.SCN-) AT 188 AND 290 K [J].

BARTOSZAK, E ;

JASKOLSKI, M ;

GRECH, E ;

GUSTAFSSON, T ;

OLOVSSON, I .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1994, 50 :358-363

[4] X-RAY, FOURIER-TRANSFORM INFRARED, H-1 AND C-13 NUCLEAR-MAGNETIC-RESONANCE, AND PM3 STUDIES OF (N-H...N)+ AND (O-H...O)- INTRAMOLECULAR HYDR OGEN BONDS IN A COMPLEX OF 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE WITH MALEIC-ACID [J].

BARTOSZAK, E ;

DEGASZAFRAN, Z ;

GRUNDWALDWYSPIANSKA, M ;

JASKOLSKI, M ;

SZAFRAN, M .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (12) :2085-2094

[5] LUPINEN-ALKALOIDE .8. ZUR KONFIGURATIONSBESTIMMUNG VON CHINOLIZIDIN-DERIVATEN [J].

BOHLMANN, F .

CHEMISCHE BERICHTE-RECUEIL, 1958, 91 (10) :2157-2167

[6]

BRZEZINSKI B, 1991, J CHEM SOC PERK T, V857, P1267

[7]

ECKART J, 1992, SPECTROCHIM ACTA A, V48, P271

[8] PERI INTERACTIONS - X-RAY CRYSTALLOGRAPHIC STUDY OF STRUCTURE OF 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE [J].

EINSPAHR, H ;

ROBERT, JB ;

MARSH, RE ;

ROBERTS, JD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (AUG15) :1611-1617

[9] BOHLMANN BANDS - REASSESSMENT [J].

ERNSTBRUNNER, EE ;

HUDEC, J .

JOURNAL OF MOLECULAR STRUCTURE, 1973, 17 (02) :249-256

[10] NEW EXAMPLE OF A SYMMETRICAL NHN HYDROGEN-BOND IN PROTONATED 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE (DMAN) [J].

GLOWIAK, T ;

MALARSKI, Z ;

SOBCZYK, L ;

GRECH, E .

JOURNAL OF MOLECULAR STRUCTURE, 1992, 270 :441-447