Synthesis of the first sulfido-bridged octahedral rhenium(III) aqua ion [Re6S8(H2O)6]2+

被引：24

作者：

Fedin, VP

Virovets, AA

Sykes, AG

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

INORGANICA CHIMICA ACTA | 1998年 / 271卷 / 1-2期

关键词：

crystal structures; rhenium cluster; sulfido-bridged; aqua form; Re6S8 core complexes;

D O I：

10.1016/S0020-1693(97)05935-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new high-yield synthesis of water-soluble salts of [Re6S8Cl6](4-) and a related X-ray crystal structure are presented. The synthesis and characterisation of the first sulfido-bridgred octahedral rhenium(III) aqua ion [Re6S8(H2O)(6)](2+) is described. (C) 1998 Elsevier Science S.A.

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页码：228 / 230

页数：3

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