Synthesis of 2,3,4,5-tetra-O-methyl-D-glucono-1,6-lactone as a monomer for the preparation of copolyesters

被引：19

作者：

Pinilla, IM ^{[1
]}

Martínez, MB ^{[1
]}

Galbis, JA ^{[1
]}

机构：

[1] Univ Seville, Fac Farm Quim Organ & Farmaceut, Dept Quim Organ & Farmaceut, Seville 41071, Spain

来源：

CARBOHYDRATE RESEARCH | 2003年 / 338卷 / 06期

关键词：

D-gluconic acid; protected; D-glucono-1,6-lactone, protected; L-lactide; ring-opening polymerization; copolyesters;

D O I：

10.1016/S0008-6215(02)00528-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

2,3,4,5-Tetra-O-methyl-D-glucono-1,6-lactone has been prepared as a crystalline compound in acceptable yield by two different routes. An initial assay of copolymerization with L-lactide by ring-opening polymerization was carried out. The incorporation of the carbohydrate monomer into the polymer chain was about 2%. (C) 2003 Elsevier Science Ltd. All rights reserved.

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页码：549 / 555

页数：7

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