Orthogonal Multiple Click Reactions in Synthetic Polymer Chemistry

被引:102
作者
Tunca, Umit [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
关键词
copper catalyzed azide-alkyne cycloaddition (CuAAC); Diels-Alder; living polymerization; Michael thiol-ene; nitroxide radical coupling (NRC); nucleophilic substitution; orthogonal multifunctionalization; polymer-polymer conjugation; post-functionalization of polymer; strain promoted azide-alkyne cycloaddition (SPAAC); thiol-ene; thiol-yne; THIOL-ENE CLICK; ONE-POT SYNTHESIS; 3-MIKTOARM STAR TERPOLYMERS; SEQUENTIAL MICHAEL ADDITION; AZIDE-ALKYNE CYCLOADDITION; DIELS-ALDER REACTION; BLOCK-COPOLYMERS; POST-FUNCTIONALIZATION; HETEROGRAFT COPOLYMERS; TRIBLOCK COPOLYMERS;
D O I
10.1002/pola.27379
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This review highlights the concept of multiple click reaction strategy which is utilized for design and synthesis of well-defined complex macromolecular structures as well as multifunctionalization of well-defined polymers. This review examines the click combinations mainly from double to quadruple and additionally from the most frequently used to the least. The present review may also be regarded as an update for recent reviews dealing with specifically double and triple click reaction combinations in synthetic polymer chemistry. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 3147-3165
引用
收藏
页码:3147 / 3165
页数:19
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