Effect of Synthesis Conditions on Morphology, Structure, and Defectiveness of Few-Layer Graphene Nanoflakes

被引：5

作者：

Chernyak, S. A. ^{[1
]}

Stolbov, D. N. ^{[1
,2
]}

Maslakov, K. I. ^{[1
]}

Maksimov, S. V. ^{[1
]}

Isaikina, O. Ya. ^{[1
]}

Savilov, S. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] Ivanovo State Univ, Res Inst Nanomat, Ivanovo 153025, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2021年 / 95卷 / 03期

关键词：

graphene-like carbon nanomaterials; synthesis; low-layer graphite fragments; Raman spectroscopy; X-ray photoelectron spectroscopy; electron microscopy;

D O I：

10.1134/S0036024421030109

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of synthesis conditions and incorporation of heteroatoms on the structure and morphology of few-layer graphene nanoflakes is investigated using Raman spectroscopy, X-ray photoelectron spectroscopy, and electron microscopy. It is found that doping with nitrogen forms defects inside graphene layers, while incorporation of silicon in contrast results in their bending and the formation of interlayer defects. Increasing the synthesis temperature reduces the number of defects in the material via graphitization and increase in the number of layers.

引用

页码：558 / 564

页数：7

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