Cu(BTC)-MOF catalyzed multicomponent reaction to construct 1,4-disubstituted-1,2,3-triazoles

被引：24

作者：

Jia, Xiangru ^{[1
]}

Xu, Guangli ^{[1
]}

Du, Zhengyin ^{[1
]}

Fu, Ying ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Gansu, Peoples R China

来源：

POLYHEDRON | 2018年 / 151卷

基金：

中国国家自然科学基金;

关键词：

Cu(BTC)-MOF; Triazoles; Multicomponent reaction; One-pot reaction; Click reaction; METAL-ORGANIC FRAMEWORKS; CLICK CHEMISTRY; 1,3-DIPOLAR CYCLOADDITION; 3-COMPONENT REACTION; SOLID-PHASE; 1,2,3-TRIAZOLES; ALKYNES; BRIDGE; AZIDES;

D O I：

10.1016/j.poly.2018.05.058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cu(BTC)-MOF catalyzed one-pot, three-component reaction of terminal alkynes, halides and sodium azide to form 1,4-disubstituted-1,2,3-triazoles was investigated. It was conducted in methanol under room temperature with good to excellent product yields. The Cu(BTC)-MOF catalyst could be easily recovered by filtration and be reused at least three recycles with no significant decrease in the yield. The method was demonstrated to be a truly green process with sustainability and economics. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：515 / 519

页数：5

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