Synthesis of 1,2-aminoalcohols by Ti(IV)-catalyzed photohydroxymethylation of chiral aldimines

被引:4
|
作者
Griesbeck, AG [1 ]
Buhr, S [1 ]
Lex, J [1 ]
机构
[1] Univ Koln, Inst Organ Chem, Greinstr 4, D-50939 Koln, Germany
关键词
D O I
10.1016/S0040-4039(98)00339-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The N-(alpha-phenylethyl) alkylated aldimines 3a-c are conveniently hydroxymethylated with moderate diastereoselectivities by means of irradiation in methanolic solution in the presence of titanium(IV)chloride. (C) 1998 Elsevier Science Ltd. All rights reserved.
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收藏
页码:2535 / 2536
页数:2
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