Coordination of a Ru(II)-complex to a tetrafunctional P-ligand: a model for Ru-P carbosilane dendrimers

被引：11
作者：
Beerens, HI
Wijkens, P
Jastrzebski, JTBH
Verpoort, F
Verdonck, L
van Koten, G
机构：
[1] Univ Ghent, Dept Inorgan & Phys Chem, Organomet & Catalysis Div, B-9000 Ghent, Belgium
[2] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 603卷 / 02期
关键词：
carbosilane dendrimers; phosphines; ruthenium(II)-complexes; metalations;
D O I：
10.1016/S0022-328X(00)00186-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Organophosphine-functionalised carbosilane (CS) dendrimers (5, 6) can be synthesised in high yield. Furthermore, new kinds of metallodendrimers (7, 8) are obtained by coordination of a Ru(II) complex, containing the tridentate triamine ligand: 2,6-bis[(dimethylamino)methyl]pyridine, to these P-functionalised CS-dendrimers. (C) 2000 Elsevier Science S.A. All rights reserved.
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收藏
页码：244 / 248
页数：5
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