Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy

被引：126

作者：

Kolokolov, Daniil I. ^{[1
,2
]}

Jobic, Herve ^{[1
]}

Stepanov, Alexander G. ^{[2
]}

Guillerm, Vincent ^{[3
]}

Devic, Thomas ^{[3
]}

Serre, Christian ^{[3
]}

Ferey, Gerard ^{[3
]}

机构：

[1] Univ Lyon 1, CNRS, IRCELYON, UMR 5256, F-69626 Villeurbanne, France

[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

[3] Univ Versailles St Quentin en Yvelines, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 28期

基金：

俄罗斯基础研究基金会;

关键词：

metal-organic frameworks; microporous materials; molecular dynamics; NMR spectroscopy; METAL-ORGANIC FRAMEWORK; ELASTIC NEUTRON-SCATTERING; MOLECULAR-DYNAMICS; COORDINATION POLYMERS; FORCE-FIELD; MOF-5; ADSORPTION; SIMULATION; DIFFUSION; SOLIDS;

D O I：

10.1002/anie.201001238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation Presentation Rotational dynamics of benzene rings in the flexible MIL-53 and rigid MIL-47 frameworks was investigated by 2H NMR spectroscopy. In both cases, 180° flips are observed, and the flipping rate is higher in MIL-53. To simulate experimental spectra (left), consideration of the quadrupolar interaction alone is not sufficient (middle); the paramagnetic effect must also be taken into account (right). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4791 / 4794

页数：4

共 44 条

[41] Dynamics and disposition of benzene guest molecules in the micropore channels of a flexible metal-organic framework studied by 2H NMR and X-ray crystallography
Ratcliffe, CI
Soldatov, DV
Ripmeester, JA
MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 73 (1-2) : 71 - 79
[42] Evidence of CO2 molecule acting as an electron acceptor on a nanoporous metal-organic-framework MIL-53 or Cr3+(OH)(O2C-C6H4-CO2)
Vimont, Alexandre
Travert, Arnaud
Bazin, Philippe
Lavalley, Jean-Claude
Daturi, Marco
Serre, Christian
Ferey, Gerard
Bourrelly, Sandrine
Llewellyn, Philip L.
CHEMICAL COMMUNICATIONS, 2007, (31) : 3291 - 3293
[43] Molecular dynamics of poly(L-lactide) biopolymer studied by wide-line solid-state 1H and 2H NMR spectroscopy
Nozirov, F
Nazirov, A
Jurga, S
Fu, RQ
SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2006, 29 (04) : 258 - 266
[44] Coherent D2 rotational tunneling and incoherent D2 dynamics in a solid non-classical RuD2 complex studied by 2H solid state NMR spectroscopy
Wehrmann, F
Fong, TP
Morris, RH
Limbach, HH
Buntkowsky, G
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (17) : 4033 - 4041

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