Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy

被引：126
|
作者：
Kolokolov, Daniil I. [1 ,2 ]
Jobic, Herve [1 ]
Stepanov, Alexander G. [2 ]
Guillerm, Vincent [3 ]
Devic, Thomas [3 ]
Serre, Christian [3 ]
Ferey, Gerard [3 ]
机构：
[1] Univ Lyon 1, CNRS, IRCELYON, UMR 5256, F-69626 Villeurbanne, France
[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
[3] Univ Versailles St Quentin en Yvelines, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 28期
基金：
俄罗斯基础研究基金会;
关键词：
metal-organic frameworks; microporous materials; molecular dynamics; NMR spectroscopy; METAL-ORGANIC FRAMEWORK; ELASTIC NEUTRON-SCATTERING; MOLECULAR-DYNAMICS; COORDINATION POLYMERS; FORCE-FIELD; MOF-5; ADSORPTION; SIMULATION; DIFFUSION; SOLIDS;
D O I：
10.1002/anie.201001238
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chemical Equation Presentation Rotational dynamics of benzene rings in the flexible MIL-53 and rigid MIL-47 frameworks was investigated by 2H NMR spectroscopy. In both cases, 180° flips are observed, and the flipping rate is higher in MIL-53. To simulate experimental spectra (left), consideration of the quadrupolar interaction alone is not sufficient (middle); the paramagnetic effect must also be taken into account (right). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4791 / 4794
页数：4
相关论文
共 44 条
  • [31] Deuterium exchange dynamics in Zr2NiD4.8 studied by 2H MAS NMR spectroscopy
    Hwang, Son-Jong, 1600, Elsevier Ltd (645):
  • [32] Deuterium exchange dynamics in Zr2NiD4.8 studied by 2H MAS NMR spectroscopy
    Kim, Chul
    Hwang, Son-Jong
    Bowman, Robert C., Jr.
    Sorby, Magnus H.
    Hauback, Bjorn
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 645 : S361 - S364
  • [33] Dynamics and Separation-based Adsorption of Binary Mixtures of CH4, CO2 and H2S on MIL-47: GCMC and MD Studies
    Shahsavani, Abbas
    Ahadi, Zohreh
    Sokhanyaran, Vahid
    Taghizadeh, Maryam
    Hadei, Mostafa
    Lakmehsari, Muhammad Shadman
    JOURNAL OF NANOANALYSIS, 2019, 6 (01): : 48 - 59
  • [34] Structure and dynamics of the aliphatic cholesterol side chain in membranes as studied by 2H NMR spectroscopy and molecular dynamics simulation
    Vogel, Alexander
    Scheidt, Holger A.
    Baek, Dong Jae
    Bittman, Robert
    Huster, Daniel
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (05) : 3730 - 3738
  • [35] Sites and dynamics of hydrogen and deuterium in V-H-D alloys studied by 1H and 2H NMR
    Bandyopadhyay, B
    Hayashi, S
    PHYSICAL REVIEW B, 1999, 60 (14): : 10302 - 10315
  • [36] Self and Transport Diffusivity of CO2 in the Metal-Organic Framework MIL-47(V) Explored by Quasi-elastic Neutron Scattering Experiments and Molecular Dynamics Simulations
    Salles, Fabrice
    Jobic, Herve
    Devic, Thomas
    Llewellyn, Philip L.
    Serre, Christian
    Ferey, Gerard
    Maurin, Guillaume
    ACS NANO, 2010, 4 (01) : 143 - 152
  • [37] Cation dynamics in pyridinium nitrate and bis-thiourea pyridinium nitrate inclusion compound studied by 2H NMR spectroscopy
    Pajzderska, A.
    Fojud, Z.
    Goc, R.
    Wasicki, J.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (15)
  • [38] Facile synthesis of defect induced CeO2/MIL-53(Fe) nanocatalyst: Strategically switching the charge transfer dynamics for remarkable enhancement of photocatalytic Bisphenol A degradation and H2 evolution
    Sahoo, Ugrabadi
    Pattnayak, Samarjit
    Choudhury, Shubhalaxmi
    Aparajita, Pragnyashree
    Pradhan, Dillip Kumar
    Hota, Garudadhwaj
    APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2024, 343
  • [39] Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53
    Férey, G
    Latroche, M
    Serre, C
    Millange, F
    Loiseau, T
    Percheron-Guégan, A
    CHEMICAL COMMUNICATIONS, 2003, (24) : 2976 - 2977
  • [40] CONFORMATION AND DYNAMICS OF THE DEOXYRIBOSE RINGS OF A (NOGALAMYCIN)2-D(5'-GCATGC)2 COMPLEX STUDIED IN SOLUTION BY H-1-NMR SPECTROSCOPY
    SEARLE, MS
    WAKELIN, LP
    BIOCHEMICAL JOURNAL, 1990, 269 (02) : 341 - 346
12345