Iodomanganesecorrole -: a stable MnIV-I species

被引：31

作者：

Broering, Martin ^{[1
]}

Hell, Christian ^{[1
]}

Brandt, Carsten D. ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 18期

关键词：

D O I：

10.1039/b700411g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first compound with a Mn-IV-I bond has successfully been prepared by oxidation of a manganese(III) corrole with molecular iodine and was structurally characterized by X-ray diffraction.

引用

页码：1861 / 1862

页数：2

共 16 条

[11] Spin transition in a manganese(III) porphyrin cation radical, its transformation to a dichloromanganese(IV) porphyrin, and chlorination of hydrocarbons by the latter [J].

Kaustov, L ;

Tal, ME ;

Shames, AI ;

Gross, Z .

INORGANIC CHEMISTRY, 1997, 36 (16) :3503-3511

[12] A STRUCTURALLY CHARACTERIZED DICHLORO-MANGANESE(IV) COMPLEX CAPABLE OF HALOGENATING ALKENES [J].

LAW, NA ;

MACHONKIN, TE ;

MCGORMAN, JP ;

LARSON, EJ ;

KAMPF, JW ;

PECORARO, VL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :2015-2016

[13] A trinuclear complex containing MnIIMnIIIMnIV, radicals, quinone and chloride ligands potentially relevant to PSII [J].

Mukherjee, C ;

Weyhermüller, T ;

Wieghardt, K ;

Chaudhuri, P .

DALTON TRANSACTIONS, 2006, (18) :2169-2171

[14] Novel aspects of corrole chemistry [J].

Nardis, S ;

Monti, D ;

Paolesse, R .

MINI-REVIEWS IN ORGANIC CHEMISTRY, 2005, 2 (04) :355-372

[15] Manganese(III) and manganese(IV) corroles: synthesis', spectroscopic, electrochemical and X-ray structural characterization [J].

Ou, ZP ;

Erben, C ;

Autret, M ;

Will, S ;

Rosen, D ;

Lex, J ;

Vogel, E ;

Kadish, KM .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2005, 9 (06) :398-412

[16] Crystal structures of the pentacoordinate bromo, isocyanato, iodo, acetato and isothiocyanato complexes of the meso-tetraphenylporphyrinatomanganese cation [J].

Turner, P ;

Gunter, MJ ;

Skelton, BW ;

White, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (09) :835-851

← 1 2 →