Bending of Thin Liquid Crystal Elastomer under Irradiation of Visible Light: Finsler Geometry Modeling

被引:8
|
作者
Koibuchi, Hiroshi [1 ]
机构
[1] Ibaraki Coll, Natl Inst Technol, Dept Ind Engn, Nakane 866, Hitachinaka, Ibaraki 3128508, Japan
关键词
liquid crystal elastomer; light irradiation; dye-doped; Monte Carlo; statistical mechanics; Finsler geometry; HIERARCHICAL STRUCTURE; MONTE-CARLO; BEHAVIOR;
D O I
10.3390/polym10070757
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this paper, we show that the 3D Finsler geometry (FG) modeling technique successfully explains a reported experimental result: a thin liquid crystal elastomer (LCE) disk floating on the water surface deforms under light irradiation. In the reported experiment, the upper surface is illuminated by a light spot, and the nematic ordering of directors is influenced, but the nematic ordering remains unchanged on the lower surface contacting the water. This inhomogeneity of the director orientation on/inside the LCE is considered as the origin of the shape change that drives the disk on the water in the direction opposite the movement of the light spot. However, the mechanism of the shape change is still insufficiently understood because to date, the positional variable for the polymer has not been directly included in the interaction energy of the models for this system. We find that this shape change of the disk can be reproduced using the FG model. In this FG model, the interaction between sigma, which represents the director field corresponding to the directional degrees of LC, and the polymer position is introduced via the Finsler metric. This interaction, which is a direct consequence of the geometry deformation, provides a good description of the shape deformation of the LCE disk under light irradiation.
引用
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页数:16
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