[1.1]diborataferrocenophane:: A highly efficient Li+ scavenger

被引：59

作者：

Scheibitz, M

Winter, RF

Bolte, M

Lerner, HW

Wagner, M

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany

[2] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

[3] Univ Frankfurt, Inst Organ Chem, D-60439 Frankfurt, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 08期

关键词：

D O I：

10.1002/anie.200390245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A naked lithium cation is efficiently trapped within the [1.1]diborataferrocenophane dianion [1]2-, but released upon electrochemical oxidation of the ferrocene moieties. The complex [1-Li]Li([12]crown4)2 provides the first experimental evidence for a theoretically predicted ferrocene⋯Li+ complex in which the Li+ ion is laterally bound to the Fe atom.

引用

页码：924 / +

页数：5

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