Factors influencing the thermal stability of azo and bisazo compounds

被引：22

作者：

Kazem-Rostami, Masoud ^{[1
]}

机构：

[1] Macquarie Univ, Fac Sci & Engn, N Ryde, NSW 2109, Australia

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2020年 / 140卷 / 02期

关键词：

Azo; Bisazo; Thermal stability; Thermal decomposition; Thermolysis; Troger base; DIAZONIUM SALT REACTIONS; SPECTRAL CHARACTERIZATION; PHOTOCHEMICAL DECOMPOSITION; LIQUID-CRYSTAL; ACID-CHLORIDE; DYES; DERIVATIVES; COMPLEXES; TRIAZENES; CATALYST;

D O I：

10.1007/s10973-019-08884-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The present study investigates the effects of substituents, structural rigidity, tautomerism, hydrogen bonding interaction, and spatial hindrance on the thermal stability of some azo compounds including bisazo Troger base analogs (BATBAs). The relatively large structures of BATBAs allow assessing their thermal stability before reaching the sublimation or boiling point. BATBAs carry two identical azo groups per molecule resulting in an intense and detectable sign of decomposition. Unlike most azo dyes, BATBAs are not ionic and prevent the complexity of decomposition associated with simultaneous dehydration. A few commercial azo dyes are also analyzed to evaluate the generality of the conclusion. [GRAPHICS] .

引用

页码：613 / 623

页数：11

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