Crystal structure, vibrational spectroscopy and optical properties of a one-dimensional organicinorganic hybrid perovskite of [NH3CH2CH(NH3)CH2]BiCl5

被引：69

作者：

Abdel-Aal, Seham K. ^{[1
]}

Abdel-Rahman, Ahmed S. ^{[1
]}

Gamal, Wafia M. ^{[1
]}

Abdel-Kader, Mohamed ^{[1
]}

Ayoub, Hany S. ^{[2
]}

El-Sherif, Ashraf F. ^{[2
]}

Kandeel, M. F. ^{[2
]}

Bozhko, S. ^{[3
]}

Yakimov, E. E. ^{[4
]}

Yakimov, E. B. ^{[4
,5
]}

机构：

[1] Cairo Univ, Fac Sci, Phys Dept, Giza 12613, Egypt

[2] Mil Tech Coll, Cairo, Egypt

[3] RAS, ISSP, Chernogolovka, Russia

[4] RAS, Inst Microelect Technol, Chernogolovka 142432, Russia

[5] Natl Univ Sci & Technol MISiS, Moscow, Russia

来源：

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS | 2019年 / 75卷

关键词：

one-dimensional hybrid perovskite; Bi halide perovskite; optical properties; vibrational spectroscopy; crystal structure; CHLORIDE COMPLEXES; PHASE-TRANSITION; PHOTOLUMINESCENCE; EFFICIENT; LENGTHS; TRIHALIDE;

D O I：

10.1107/S2052520619011314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work the crystal structure by single crystal X-ray measurement and optical properties of 1D propane-1,2-diammonium pentachlorobismuthate [NH3CH2CH(NH3)CH3]BiCl5 organic-inorganic hybrid perovskite are presented. It is prepared by mixing ethanolic solution of equimolar ratios (1:1) of its basic components. The title compound crystallized in the noncentrosymmetric orthorhombic space group Pca2(1) with Z = 8 molecules per unit cell. The unit-cell parameters are a = 19.8403 (7) angstrom, b = 6.3303 (2) angstrom, c = 19.0314 (7) angstrom. The vibrational spectra are studied by Raman and infrared spectroscopy. The optical properties show a strong absorption in the ultraviolet region, the band gap energy E-g is found to be 3.15 eV. Cathodoluminescence measurements are also discussed.

引用

页码：880 / 886

页数：7

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