Lagrangian analysis of the transport and processing of agricultural runoff in the lower Maumee River and Maumee Bay

Lagrangian analyses is used to evaluate the processing of nutrients and sediments during storm runoff events as water moved from the Maumee River loading station at Waterville, OH through the lower river, Maumee Bay and into Lake Erie's western basin. Chemical signatures of storm water at Waterville were used in combination with frequent collections of water at transects along the flow paths to evaluate processing. These signatures consisted of the contrasting chemographs of conservative parameters (chloride and sulfate), dissolved nutrients (dissolved reactive phosphorus (DRP) and nitrate) and particulate substances (suspended solids (SS) and particulate phosphorus (PP)). During low flow, sharp drops in concentrations of chloride and sulfate indicated that mixing zones between river water and bay/lake water occurred at the river mouth. During high flows, the location of the mixing zone between riverine and bay/lake water was indicated by the margin of storm-event sediment plumes, with larger storms extending further into the lake. Steep concentration gradients of DRP and nitrate between high storm water concentrations and low bay/lake water concentrations were also present at the plume margin. The large areas of storm water inside the plume margin contained high DRP and nitrate concentrations but relatively low SS and PP concentrations, due to SS and PP deposition along the flow paths. Because this deposition occurred in water with high DRP concentrations, little of the bioavailable PP was likely to have been released prior to deposition. This storm runoff water provides excellent media for algal growth. (C) 2014 International Association for Great Lakes Research. Published by Elsevier B.V. All rights reserved.