Self-assembly of a redox-active bolaamphiphile into supramolecular vesicles

被引:7
|
作者
Rothenbuhler, Simon [1 ]
Bosch, Caroline D. [1 ]
Langenegger, Simon M. [1 ]
Liu, Shi-Xia [1 ]
Haner, Robert [1 ]
机构
[1] Univ Bern, Dept Chem & Biochem, Freiestr 3, CH-3012 Bern, Switzerland
基金
瑞士国家科学基金会;
关键词
AMPHIPHILIC PYRENE OLIGOMERS; POLYMERS; BIOMATERIALS; ORGANIZATION; POLYMERIZATION; NANOSHEETS; DIVERSITY; STACKS;
D O I
10.1039/c8ob02106f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis and self-assembly of a water-soluble bolaamphiphilic cyclopenta[hi]aceanthrylene derivative is described. Self-assembly in aqueous medium leads to the formation of supramolecular vesicles with intense absorption bands over an extended range of the UV/vis spectral region and a narrow HOMO-LUMO bandgap of 1.65 eV.
引用
收藏
页码:6886 / 6889
页数:4
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