Self-assembly of a redox-active bolaamphiphile into supramolecular vesicles

被引:7
|
作者
Rothenbuhler, Simon [1 ]
Bosch, Caroline D. [1 ]
Langenegger, Simon M. [1 ]
Liu, Shi-Xia [1 ]
Haner, Robert [1 ]
机构
[1] Univ Bern, Dept Chem & Biochem, Freiestr 3, CH-3012 Bern, Switzerland
基金
瑞士国家科学基金会;
关键词
AMPHIPHILIC PYRENE OLIGOMERS; POLYMERS; BIOMATERIALS; ORGANIZATION; POLYMERIZATION; NANOSHEETS; DIVERSITY; STACKS;
D O I
10.1039/c8ob02106f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis and self-assembly of a water-soluble bolaamphiphilic cyclopenta[hi]aceanthrylene derivative is described. Self-assembly in aqueous medium leads to the formation of supramolecular vesicles with intense absorption bands over an extended range of the UV/vis spectral region and a narrow HOMO-LUMO bandgap of 1.65 eV.
引用
收藏
页码:6886 / 6889
页数:4
相关论文
共 50 条
  • [1] Alkali-Metal-Ion-Directed Self-Assembly of Redox-Active Manganese(III) Supramolecular Boxes
    Gonzalez-Riopedre, Gustavo
    Bermejo, Manuel R.
    Isabel Fernandez-Garcia, M.
    Gonzalez-Noya, Ana M.
    Pedrido, Rosa
    Jesus Rodriguez-Douton, M.
    Maneiro, Marcelino
    INORGANIC CHEMISTRY, 2015, 54 (06) : 2512 - 2521
  • [2] Redox-active organometallic vesicles: Aqueous self-assembly of a diblock copolymer with a hydrophilic polyferrocenylsilane polyelectrolyte block
    Power-Billard, KN
    Spontak, RJ
    Manners, I
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (10) : 1260 - 1264
  • [3] Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly
    Wilkinson, Luke A.
    Yue, Thomas T. C.
    Massey, Emma
    White, Andrew J. P.
    Long, Nicholas J.
    DALTON TRANSACTIONS, 2019, 48 (01) : 72 - 78
  • [4] Dipole-driven self-assembly of redox-active mesogenic tetracyanoanthraquinodimethanes
    Isoda, Kyosuke
    Yasuda, Takuma
    Kato, Takashi
    JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (38) : 4522 - 4528
  • [5] Synthesis and self-assembly of a redox-active, superatom-containing polymer
    Voevodin, Anastasia
    Roy, Xavier
    Campos, Luis
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [6] Metal-driven self-assembly: the case of redox-active discrete
    Croue, V.
    Goeb, S.
    Salle, M.
    CHEMICAL COMMUNICATIONS, 2015, 51 (34) : 7275 - 7289
  • [7] Shape Complementary Coordination Self-Assembly of a Redox-Active Heteroleptic Complex
    Xuan, Jin-Jin
    Xia, Zi-Jun
    Yan, Dan-Ni
    Hu, Shao-Jun
    Zhou, Li-Peng
    Cai, Li-Xuan
    Sun, Qing-Fu
    INORGANIC CHEMISTRY, 2022, 61 (23) : 8854 - 8860
  • [8] Heparin binding induced supramolecular chirality into the self-assembly of perylenediimide bolaamphiphile
    Sharma, Poonam
    Venugopal, Akhil
    Verdi, Claudia Martinez
    Roger, Mauri Serra
    Calo, Annalisa
    Kumar, Mohit
    JOURNAL OF MATERIALS CHEMISTRY B, 2024, 12 (30) : 7292 - 7297
  • [9] Electrochemical control of the self-assembly of redox-active surfactants within microfluidic channels
    Abbott, Nicholas L.
    Liu, Xiaoyang
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [10] Butadiynyl-bridged Diphenothiazines - Redox-active Fluorophores and Self-assembly on HOPG
    Barkschat, Christa S.
    Guckenberger, Reinhard
    Mueller, Thomas J. J.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2009, 64 (06): : 707 - 718