Tetra-p-tolylantimony 4-methylbenzenesulfonate:: Synthesis and structure

被引：1

作者：

Sharutin, VV

Pakusina, AP

Egorova, IV

Ivanenko, TK

Gerasimenko, AV

Sergienko, AS

机构：

[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia

[2] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Physical Chemistry; Toluene; Carbon Atom; Antimony; Diffraction Data;

D O I：

10.1023/A:1023667500059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetra-p-tolylantimony 4-methylbenzenesulfonate (I) was synthesized via the reaction of tri-p-tolyl-bismuth bis(4-methylbenzenesulfonate) with penta-p-tolylantimony in toluene. According to the X-ray diffraction data, the antimony atoms of two individual molecules of I have a distorted trigonal bipyramidal coordination with the axial 4-methylbenzenesulfonate ligand and three equatorial tolyl ligands, one of which contains four carbon atoms disordered over two sites with the occupancy factors 0.7 and 0.3.

引用

页码：312 / 316

页数：5