Synthesis, photophysics, electrochemistry and metal ion-binding studies of rhenium(I) complexes with crown ether pendants: selective and specific binding properties for various metal ions

被引：17
|
作者：
Wong, KMC
Li, WP
Cheung, KK
Yam, YWW
机构：
[1] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Open Lab Chem Biol, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 01期
关键词：
D O I：
10.1039/b415951a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of rhenium( I) diimine complexes with crown ether pendants has been synthesized and the photophysical and electrochemical behaviour studied. By variation of the cavity size and donor atoms of the crown ether, the complexes showed selective and specific binding properties for various metal cations of different sizes and different degrees of hardness and softness. The X-ray crystal structure of one of the complexes has also been determined.
引用
收藏
页码：165 / 172
页数：8
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