Four new esters, namely n-decan-3-olyl pent-3'-en-1'-oate, n-hexadec-9,11-dienyl cinnamate, n-tridecanyl-hex-2',4'-dien-1'-oate, n-heneitriacont-13-en-5,10-diol hex-2'-en-1'-oate, have been isolated from the rhizomes of Curculigo orchioides and characterized by the combination of chemical reactions and spectral data analysis.