Polarization loss-enhanced honeycomb-like MoS2 nanoflowers/undaria pinnatifida-derived porous carbon composites with high-efficient electromagnetic wave absorption

被引:145
作者
Cheng, Jie [1 ]
Cai, Lei [1 ]
Shi, Yuyang [1 ]
Pan, Fei [1 ]
Dong, Yanyan [1 ]
Zhu, Xiaojie [1 ]
Jiang, Haojie [1 ]
Zhang, Xiang [1 ]
Xiang, Zhen [1 ]
Lu, Wei [1 ]
机构
[1] Tongji Univ, Sch Mat Sci & Engn, Shanghai Key Lab D&A Met Funct Mat, Shanghai 201804, Peoples R China
关键词
Undaria pinnatifida; Superb electromagnetic wave absorption; Porous structure; Sustainable and low-cost; MICROWAVE-ABSORPTION; PERFORMANCE; HYBRIDS; OXIDE; FE3O4; BAND; CONSTRUCTION; NANOSHEETS; SHELL; VS2;
D O I
10.1016/j.cej.2021.134284
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The increasingly serious electromagnetic pollution has caused an urgent demand for easy preparation, sustain-able and low-cost electromagnetic absorbing materials with super absorption capacity. Herein, inspired by the nature, spherical MoS2 nanoflowers/undaria pinnatifida-derived honeycomb-like porous carbon composites were fabricated by a simple carbonization and subsequent hydrothermal process. The unique honeycomb-like porous microstructure of undaria pinnatifida facilitates the generation of multiple scattering and reflections and the construction of interconnected conducting networks, while the rich porous structure provides a vast surface for the growth of MoS2 crystals. In addition, MoS2 significantly not only improved the impedance matching of the composites but also greatly enhanced the polarization loss due to the simultaneous growth of MoS2 nanoflowers on the surface and in the internal pores of the undaria pinnatifida. As a result, the hybrids achieved a maximum electromagnetic wave (EMW) absorption capacity with a reflection loss (RL) value of up to-75.94 dB at a thickness of only 1.68 mm. The results indicated that the C/MoS2 hybrids can be a new prospective candidate as sustainable EMW absorbers with low density and superb EMW absorption performance.
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页数:12
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共 69 条
[1]   Interfacial crystallization at the intersection of thermodynamic and geometry [J].
Bormashenko, Edward ;
Valtsifer, Viktor .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2021, 296
[2]   Banana Leaflike C-Doped MoS2 Aerogels toward Excellent Microwave Absorption Performance [J].
Cheng, Jin-Bo ;
Zhao, Hai-Bo ;
Cao, Min ;
Li, Meng-En ;
Zhang, Ai-Ning ;
Li, Shu-Liang ;
Wang, Yu-Zhong .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (23) :26301-26312
[3]   Construction of multiple interfaces and dielectric/magnetic heterostructures in electromagnetic wave absorbers with enhanced absorption performance: A review [J].
Cheng, Junye ;
Zhang, Huibin ;
Xiong, Yingfei ;
Gao, Lingfeng ;
Wen, Bo ;
Raza, Hassan ;
Wang, Hao ;
Zheng, Guangping ;
Zhang, Han ;
Zhang, Deqing .
JOURNAL OF MATERIOMICS, 2021, 7 (06) :1233-1263
[4]   Rationally regulating complex dielectric parameters of mesoporous carbon hollow spheres to carry out efficient microwave absorption [J].
Cheng, Yan ;
Li, Zhaoyong ;
Li, Yong ;
Dai, Sisi ;
Ji, Guangbin ;
Zhao, Huanqin ;
Cao, Jieming ;
Du, Youwei .
CARBON, 2018, 127 :643-652
[5]   Engineering Dielectric Loss of FeCo/Polyvinylpyrrolidone Core-Shell Nanochains@Graphene Oxide Composites with Excellent Microwave Absorbing Properties [J].
Cui, Erbiao ;
Pan, Fei ;
Xiang, Zhen ;
Liu, Zhicheng ;
Yu, Lunzhou ;
Xiong, Juan ;
Li, Xiang ;
Lu, Wei .
ADVANCED ENGINEERING MATERIALS, 2021, 23 (01)
[6]   Electrostatically self-assembled two-dimensional magnetized MXene/hollow Fe3O4 nanoparticle hybrids with high electromagnetic absorption performance and improved impendence matching [J].
Deng, Baiwen ;
Liu, Zhicheng ;
Pan, Fei ;
Xiang, Zhen ;
Zhang, Xiang ;
Lu, Wei .
JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (06) :3500-3510
[7]   Sandwich-Like Fe&TiO2@C Nanocomposites Derived from MXene/Fe-MOFs Hybrids for Electromagnetic Absorption [J].
Deng, Baiwen ;
Xiang, Zhen ;
Xiong, Juan ;
Liu, Zhicheng ;
Yu, Lunzhou ;
Lu, Wei .
NANO-MICRO LETTERS, 2020, 12 (01)
[8]  
Deng Y., 2021, APPL SURF SCI
[9]   Mace-like carbon fiber/ZnO nanorod composite derived from Typha orientalis for lightweight and high-efficient electromagnetic wave absorber [J].
Dong, Yanyan ;
Zhu, Xiaojie ;
Pan, Fei ;
Deng, Baiwen ;
Liu, Zhicheng ;
Zhang, Xiang ;
Huang, Chuang ;
Xiang, Zhen ;
Lu, Wei .
ADVANCED COMPOSITES AND HYBRID MATERIALS, 2021, 4 (04) :1002-1014
[10]   Evaluation of the microwave absorption property of flake graphite [J].
Fan, Yuzun ;
Yang, Haibin ;
Li, Minghui ;
Zou, Guangtian .
MATERIALS CHEMISTRY AND PHYSICS, 2009, 115 (2-3) :696-698