Palladium-catalysed asymmetric [4+2] cycloaddition of vinylallene with 1,3-diene

被引:35
|
作者
Murakami, M [1 ]
Minamida, R [1 ]
Itami, K [1 ]
Sawamura, M [1 ]
Ito, Y [1 ]
机构
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6068501, Japan
关键词
D O I
10.1039/b007781j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A catalytic asymmetric [4 + 2] cycloaddition reaction of a vinylallene with buta-1,3-diene was developed in which a palladium complex modified by a ferrocene-derived chiral monophosphine ligand acted as a template transferring chirality to the product.
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收藏
页码:2293 / 2294
页数:2
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