Unconventional U-shaped conformation of a bolaamphiphile embedded in a synthetic host

被引：51
作者：
Baek, Kangkyun
Kim, Youngkook
Kim, Hyunuk
Yoon, Minyoung
Hwang, Ilha
Ko, Young Ho
Kim, Kimoon [1 ]
机构：
[1] Pohang Univ Sci & Technol POSTECH, Natl Creat Res Initiat Ctr Smart Supramol, Dept Chem, Pohang 790784, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 23期
关键词：
CHARGE-TRANSFER COMPLEX; AIR-WATER-INTERFACE; CUCURBITURIL HOMOLOGS; ROTAXANE DENDRIMERS; DERIVATIVES; COMPONENTS; CHEMISTRY; BEHAVIOR; FAMILY; IONS;
D O I：
10.1039/c0cc00752h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The X-ray crystal structure of 1,12-dodecane diammonium (C(12)DA(2+)) encapsulated in cucurbit[8]uril reveals an unconventional U-shaped conformation of C(12)DA(2+), which is attributed to the favorable host-guest interactions to overcome the charge-charge repulsion of the two ammonium groups in close proximity and high internal strain.
引用
收藏
页码：4091 / 4093
页数：3
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