Liquid poly(ethylene glycol) and supercritical carbon dioxide as a biphasic solvent system for lipase-catalyzed esterification

被引：35
作者：
Reetz, MT [1 ]
Wiesenhöfer, W [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 23期
关键词：
D O I：
10.1039/b412049c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The biphasic solvent system composed of poly( ethylene glycol) (PEG) and supercritical carbon dioxide (scCO(2)) is ideally suited for the lipase-catalyzed acylation of alcohols; batch or continuous flow acylations are possible, scCO(2) being used to extract the products.
引用
收藏
页码：2750 / 2751
页数：2
相关论文
共 41 条
[1]  
[Anonymous], ANGEW CHEM
[2]  
[Anonymous], 1999, CHEM SYNTHESIS USING
[3]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[4]   Recent advances in applications of room-temperature ionic liquid/supercritical CO2 systems [J].
Dzyuba, SV ;
Bartsch, RA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (02) :148-150
[5]   Liquid poly(ethylene glycol) and supercritical carbon dioxide: A benign biphasic solvent system for use and recycling of homogeneous catalysts [J].
Heldebrant, DJ ;
Jessop, PG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (19) :5600-5601
[6]  
Holbrey JD., 1999, Clean. Prod. Process., V1, P223, DOI [10.1007/s100980050036, DOI 10.1007/S100980050036]
[7]  
Hungerhoff B, 2001, ANGEW CHEM INT EDIT, V40, P2492, DOI 10.1002/1521-3773(20010702)40:13<2492::AID-ANIE2492>3.0.CO
[8]  
2-8
[9]  
Hungerhoff B., 2001, ANGEW CHEM, V113, P2550
[10]   Impact of ionic liquid physical properties on lipase activity and stability [J].
Kaar, JL ;
Jesionowski, AM ;
Berberich, JA ;
Moulton, R ;
Russell, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (14) :4125-4131
12345