Glass-forming Ability and Corrosion Resistance of Zr-Cu-Al-Co Bulk Metallic Glass

被引:24
作者
Zhou, W. [1 ]
Weng, W. P.
Hou, J. X. [1 ]
机构
[1] Soochow Univ, Shagang Sch Iron & Steel, Suzhou 215021, Peoples R China
基金
中国国家自然科学基金;
关键词
Bulk metallic glass; Co-addition; Glass-forming ability; Corrosion resistance; MECHANICAL-PROPERTIES; COMPOSITES; ALLOYS; MICROSTRUCTURE; ENHANCEMENT; PLASTICITY; BEHAVIOR;
D O I
10.1016/j.jmst.2015.12.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Investigations were carried out to examine the effects of Co addition on the glass-forming ability (GFA) and corrosion resistance of Zr46Cu46Al8 bulk metallic glass in chloride-containing solution. It is found that the GFA of (Zr46Cu46Al8)(100-x)Co-x (x = 0, 1, 2, and 4 at.%) alloys reduces with the increase in Co content and correlates well with the parameters, such as the supercooled liquid region width Delta T-x, the reduced glass transition temperature T-rg and gamma. The corrosion resistance is however found to be enhanced with the increase in Co concentration. The addition of Co causes the enrichment of Zr and Al, but depletes Cu in the surface films, which effectively enhances the corrosion potential and lowers the corrosion current density. Copyright (C) 2016, The editorial office of Journal of Materials Science & Technology. Published by Elsevier Limited. All rights reserved.
引用
收藏
页码:349 / 354
页数:6
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