Recent Advances in Organocatalytic Asymmetric Cycloaddition Reactions Through Ortho-Quinone Methide Scaffolds

被引：40

作者：

Ma, Yu-Hong ^{[1
]}

He, Xiao-Yu ^{[1
]}

Yang, Qing-Qing ^{[1
]}

Boucherif, Amina ^{[2
]}

Xuan, Jun ^{[3
]}

机构：

[1] China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Hubei, Peoples R China

[2] Aboubeker Belkaid Univ, Dept Biol, BP119, Tilimsen 13000, Algeria

[3] Anhui Univ, Coll Chem & Chem Engn, Anhui Prov Key Lab Chem Inorgan Organ Hybrid Func, Hefei 230601, Anhui, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 10卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Organocatalysis; ortho-quinone methides; cycloaddition; asymmetric catalysis; oxa-heterocylces; ENANTIOSELECTIVE 4+2 CYCLOADDITION; DIELS-ALDER REACTIONS; STABLE SULFUR YLIDES; PHOSPHINE CATALYSIS; O-HYDROXYSTYRENES; ANNULATION; GENERATION; DIHYDROCOUMARINS; ACCESS; ACID;

D O I：

10.1002/ajoc.202100141

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review summarizes the very recent advances in organocatalytic asymmetric cycloaddition reactions involving ortho-quinone methides (o-QMs), a family of versatile species that have proven useful in a broad range of reactions to afford diverse chiral molecules. In the past years, different kinds of organocatalysts have been developed into a privileged class of catalytic systems in asymmetric synthesis. A number of remarkable achievements have been made by many groups around the world. Due to length limitation, this review only summarizes those works published from January 2016 to December 2020. Meanwhile, catalytic systems which combine metal catalysts and organocatalysts will not be discussed in this review.

引用

页码：1233 / 1250

页数：18

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