共 24 条
Viscosity and density of water plus ethyl acetate plus ethanol mixtures at 298.15 and 318.15 k and atmospheric pressure
被引:77
作者:

Pires, Rui M.
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Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal

Costa, Henrique F.
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Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal

Ferreira, Abel G. M.
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Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal

Fonseca, Isabel M. A.
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Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal
机构:
[1] Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal
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D O I:
10.1021/je600565m
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
The viscosities and densities of the ternary mixtures water + ethyl acetate + ethanol and their constituent binaries have been measured at 298.15 and 318.15 K and atmospheric pressure. The excess molar volumes, V-m(E), and viscosity deviations, Delta eta, were calculated from density and viscosity, respectively. A rational function due to Myers and Scott was used to describe the composition dependence of these properties. To describe the ternary system, binary pair additivity and the Pando et al. rational functions for the ternary contributions (Delta eta(T) and V-T(E)) were considered.
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页码:1240 / 1245
页数:6
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