Viscosity and density of water plus ethyl acetate plus ethanol mixtures at 298.15 and 318.15 k and atmospheric pressure

被引:77
作者
Pires, Rui M. [1 ]
Costa, Henrique F. [1 ]
Ferreira, Abel G. M. [1 ]
Fonseca, Isabel M. A. [1 ]
机构
[1] Univ Coimbra, Dept Engn Quim, P-3030290 Coimbra, Portugal
关键词
D O I
10.1021/je600565m
中图分类号
O414.1 [热力学];
学科分类号
摘要
The viscosities and densities of the ternary mixtures water + ethyl acetate + ethanol and their constituent binaries have been measured at 298.15 and 318.15 K and atmospheric pressure. The excess molar volumes, V-m(E), and viscosity deviations, Delta eta, were calculated from density and viscosity, respectively. A rational function due to Myers and Scott was used to describe the composition dependence of these properties. To describe the ternary system, binary pair additivity and the Pando et al. rational functions for the ternary contributions (Delta eta(T) and V-T(E)) were considered.
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页码:1240 / 1245
页数:6
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