Hydrothermal synthesis and characterizaton of [CH3NH3][NH3(CH2)6NH3]H3[P2Mo2W16O62] • H2O

被引：0

作者：

Liu, ZR ^{[1
]}

Wang, L

Chen, BG

Xu, L

Wang, EB

Xing, Y

Jia, HQ

Lin, YH

机构：

[1] Inner Mongolia Univ Nationalities, Coll Chem, Tongliao 028043, Peoples R China

[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

[3] Chinese Acad Sci, Inst Appl Chem, Changchun 130022, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 05期

关键词：

hydrothermal synthesis; crystal structure; tungstomolybdophosphate; (Ed; S; F; X);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel heteropoly tungstomolybdophosphate, [CH3NH3] [NH3 (CH2) 6NH3]H-3[P2Mo2W16O62].H2O has been synthesized and characterized by elemental analysis, IR, TGA-DSC and single-crystal Xray structure analysis. Crystal data: monoclinic, space group P2(1)/m, a = 1.259 6(3) nm, b = 1.871 5 (4) nm, c = 1.981 6(4) nm, alpha = gamma = 90degrees, beta = 90.16 (3)degrees, V = 4.671 (2) nm(3), Z = 2, M-r = 4 358.66, D-c = 3.100 g.cm(-3), mu = 19.978 mm(-1), F(000) = 3 792, R = 0.083 5, R-w = 0.2026. The structure analysis shows that a kind of micropore with size of 0.736 4 nm X 0.835 4 nm was formed in the crystal structure.

引用

页码：772 / 775

页数：4

共 11 条

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